The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H<sub>2</sub>O)]ClO<sub>4</sub> and K<sub>3</sub>[Fe(CN)<sub>6</sub>] - Concepedia

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The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H<sub>2</sub>O)]ClO<sub>4</sub> and K<sub>3</sub>[Fe(CN)<sub>6</sub>]

136

Citations

13

References

1995

Year

Hitoshi Miyasaka, Naohide Matsumoto, Hisashi O̅kawa, Nazzareno Re, Emma Gallo, Carlo Floriani

Angewandte Chemie International Edition in English

Magnetic PropertiesTwo-dimensional NetworkEngineeringLow-dimensional MagnetismMagnetic ResonanceOne-dimensional MagnetismChemistryTitle CompoundMagnetic MaterialsLinear Chain CompoundInorganic CompoundMagnetismQuantum MaterialsInorganic ChemistryPhysicsLow-dimensional SystemsMagnetic MaterialFerromagnetismMolecule-based MagnetNatural SciencesCondensed Matter PhysicsApplied PhysicsMetamagnetic PropertiesCyclic Tetrameric UnitsTwo‐dimensional Network StructureMetal Chain Compound

Abstract

Cyclic tetrameric units (··Mn-NC-Fe-CN··)4 (depicted on the right) construct the two-dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.

References

	Year	Citations

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