Concepedia

The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H<sub>2</sub>O)]ClO<sub>4</sub> and K<sub>3</sub>[Fe(CN)<sub>6</sub>]

Hitoshi Miyasaka, Naohide Matsumoto, Hisashi O̅kawa, Nazzareno Re, Emma Gallo, Carlo Floriani

Angewandte Chemie International Edition in English · 1995 · 136 citations · 13 references

DOI

Concepts

Abstract

Cyclic tetrameric units (··Mn-NC-Fe-CN··)4 (depicted on the right) construct the two-dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.

References

13

Organic and Organometallic Molecular Magnetic Materials—Designer Magnets

Joel S. Miller, Arthur J. Epstein · Angewandte Chemie International Edition in English · 1994 · 1.3K citations

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High- <i>T</i> <sub>c</sub> Molecular-Based Magnets: Ferrimagnetic Mixed-Valence Chromium(III)-Chromium(II) Cyanides with <i>T</i> <sub>c</sub> at 240 and 190 Kelvin

Talal Mallah, S. Thiébaut, Michel Verdaguer et al. · Science · 1993 · 821 citations

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Design of metal-complex magnets. Syntheses and magnetic properties of mixed-metal assemblies {NBu4[MCr(ox)3]}x (NBu4+ = tetra(n-butyl)ammonium ion; ox2- = oxalate ion; M = Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+)

Hiroko Tamaki, Zhuang Jin Zhong, Naohide Matsumoto et al. · Journal of the American Chemical Society · 1992 · 785 citations

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The Active Sites in Manganese‐Containing Metalloproteins and Inorganic Model Complexes

Karl Wieghardt · Angewandte Chemie International Edition in English · 1989 · 708 citations

, , +16

A Molecular-Based Magnet with a Fully Interlocked Three-Dimensional Structure

Humberto O. Stumpf, Pei Yu, Olivier Kahn et al. · Science · 1993 · 454 citations

, , +17