A Molecular-Based Magnet with a Fully Interlocked Three-Dimensional Structure

TLDR

The authors synthesized a complex (rad)₂Mn₂[Cu(opba)]₃(DMSO)₂·2H₂O containing Mn(II), Cu(II), and nitroxide radicals. The crystal features two interlocked graphite‑like Mn–Cu hexagonal networks with antiferromagnetically coupled Mn/Cu and Cu–rad chains, and exhibits magnetic ordering below 22.5 K.

Abstract

A compound has been synthesized with the formula (rad)(2)Mn(2)[Cu(opba)](3)(DMSO)(2).2H(2)O, where rad(+) is 2-(4-N-methylpyridinium)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, opba is orthophenylenebis(oxamato), and DMSO is dimethyl sulfoxide. It consists of two nearly perpendicular graphite-like networks with edge-sharing Mn(II)(6)Cu(II)(6) hexagons. The two networks are fully interlocked with the same topological relationship as that between adjacent rings of a necklace. The compound has three kinds of spin carriers: Mn(II) and Cu(II) ions, antiferromagnetically coupled through oxamato bridges, and rad(+) radical cations, bridging the Cu(II) ions through the nitronyl nitroxide groups and forming Cu-rad chains. The temperature dependence of the magnetization reveals that below 22.5 K, the compound behaves as a magnet.