Chemische Berichte · 1987 · 14 citations · 2 references
Natural SciencesChemistryOrganometallic ChemistryReaction EngineeringSynthetic Medicinal ChemistrySulfur ChemistrySulfur CompoundsStepwise Reaction Pathways
A Simple Method for the Preparation of Stannylated Diamino‐sulfanes On heating sulfinimidamides t BuS(NRNR 1 (SnMe 3 ) ( 3 ) (obtained in the stepwise reaction of sulfur diimides 1 with tert ‐butyllithium and chlorotrimethylstannane) a reductive elimination of isobutene takes place and the stannylated diaminosulfanes (Me 3 Sn)R 1 NSNHR 2 ( 4 ) are formed in good yields. Some properties of these new compounds are reported.
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