Concepedia

Organo-Directed Synthesis of Manganese Vanadates with Variable Stoichiometry and Dimensionality:  1-D [(Hen)<sub>2</sub>Mn(VO<sub>3</sub>)<sub>4</sub>], 2-D [H<sub>2</sub>en]<sub>2</sub>[Mn(VO<sub>3</sub>)<sub>6</sub>], and 3-D [H<sub>2</sub>en][MnF(VO<sub>3</sub>)<sub>3</sub>]

T.S.-C. Law, Ian D. Williams

Chemistry of Materials · 2000 · 37 citations · 13 references

DOI

Concepts

Abstract

View of the open framework of the [H2en][MnF(VO3)3] one of a new family of organically templated manganese vanadates synthesized under mild conditions. The compound shown here has novel hexavanadate rings connecting manganese fluoride pillars and forming microchannels which contain the organic counterions.

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