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Solid-State Coordination Chemistry: The Self-Assembly of Microporous Organic-Inorganic Hybrid Frameworks Constructed from Tetrapyridylporphyrin and Bimetallic Oxide Chains or Oxide Clusters
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1999
Year
Supramolecular AssemblyEngineeringOxide ClustersMetal OxideOrganic ChemistryChemistryInorganic MaterialBimetallic Oxide ChainsMetal-organic PolyhedronMaterials ScienceInorganic ChemistryPorphyrin SubunitsCovalent Bonded FrameworkCatalysisMetal-organic FrameworksInorganic SynthesisAppropriate MSelf-assemblyFunctional MaterialsSolid-state Coordination ChemistryOrganic-inorganic Hybrid Material
The hydrothermal reactions of MoO(3), tetrapyridylporphyrin (tpypor), water, and the appropriate M(II) precursor yield the first examples of three-dimensional framework materials constructed from metal oxide and porphyrin subunits. The picture shows a section of [{Fe(tpypor)}(3)Fe(Mo(6)O(19))(2)] small middle dotx H(2)O with the [Fe(8)(tpypor)(6)](8+) building block of the cationic framework and the entrained {Mo(6)O(19)}(2-) cluster.