The Journal of Organic Chemistry · 2009 · 120 citations · 40 references
Natural SciencesChemistryAnalytical ChemistryOrganic ChemistrySensorsChemical SensorsFluorescence SpectroscopyMolecular SensorsPhotochemical KineticsPhotochemistryPhotophysics Of Fluorescent ProbesFluorescence Resonance Energy TransferFluorescence-based SensingFluorescent Molecular SensorsFluorescent SensingFluorescent SensorsPhotochemical Reaction MechanismsSensing In Aqueous MediaSulfite Chemistry
A fluorescent chemodosimeter containing a guanidiniocarbonylpyrrole and a 9-(aminomethyl)anthracene moiety has been synthesized. The sensor exhibits ratiometric fluorescence changes for SO(3)(2-) over other anions in 90% water/DMSO. The interesting ratiometric fluorescent changes for SO(3)(2-) are attributed to the fluorescence resonance energy transfer (FRET) and the SO(3)(2-) complex induced photochemical reaction.
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