Petroleum Science and Technology · 2005 · 38 citations · 3 references
EngineeringMaterials EngineeringMaterials ScienceFormation EvaluationPetrophysicsThermal AnalysisGelsPhysicochemical CharacterizationCrude Oil Composition EffectsGel PointMaterial Flow PropertiesPour PointThermodynamic ForcesWax PrecipitationWax Precipitation ThermodynamicsWaxy Crude Oil Phase Behavior
Abstract: The amount of precipitated wax is one of the key factors that governs the flow properties of waxy crudes. Experimental results of 24 crudes have shown that approximately 2 wt% precipitated wax is sufficient to cause a virgin waxy crude gelling. Accordingly, a correlation between the pour point and the temperature at which 2 wt% of wax has precipitated out from a crude oil; i.e., T c (2 wt%), and a correlation between the gel point and T c (2 wt%) have been developed. The proposed correlation of the pour point is in accordance with the correlation developed by Letoffe et al. (1995) on the basis of 14 crudes from eight countries. The development of the gel point correlation and further verification of the pour point correlation indicate that there is a relationship between the gelling of virgin waxy crudes and the amount of precipitated wax. According to these correlations and the amount of precipitated wax, which can be determined only with a little sample by thermodynamic models or Differential ...
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Crude oils: characterization of waxes precipitated on cooling by d.s.c. and thermomicroscopy
J.M. Letoffé, P. Claudy, Mustafa Verşan Kök et al. · Fuel · 1995 · 131 citations
P. Claudy, Jean-Marie Létoffé, Bernard Damin · Fuel · 1986 · 76 citations