Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy

S. Evans, J. C. Green, M. L. H. Green, A. F. Orchard, D. W. Turner

Discussions of the Faraday Society · 1969 · 75 citations · 0 references

Concepts

Abstract

The photoelectron spectra excited by helium 21·2 eV radiation in the complexes Mn(CO)5X, where X = H, Cl, Br, I, CH3, CF3, COCF3 and Mn(CO)5, have been determined. The ionization potential data are discussed in terms of a simple molecular orbital description of the electronic structures.