Facile synthesis of a surface plasmon resonance-enhanced Ag/AgBr heterostructure and its photocatalytic performance with 450 nm LED illumination

Kai Dai, Luhua Lu, Jun Dong, Ziye Ji, Guangping Zhu, Qinzhuang Liu, Zhongliang Liu, Yongxing Zhang, Dongpei Li, Changhao Liang

Dalton Transactions · 2013 · 65 citations · 32 references

Concepts

Abstract

In this paper, a plasmonic Ag/AgBr heterostructure was reduced by AgBr, which was successfully synthesized by a facile hydrothermal process at a temperature as low as 90 °C. The morphological and structural observation, crystallinity and optical performance of the products grown were carried out by using scanning electron microscopy, X-ray diffraction, energy dispersive spectrometry and UV-vis diffuse reflectance spectroscopy. The photocatalytic activities of Ag/AgBr heterostructures were evaluated by the degradation of methylene blue under 450 nm LED arrays. The results revealed that the plasmonic Ag/AgBr heterostructures exhibited much higher photocatalytic activities than pure AgBr and commercial Degussa P25. The visible-light photocatalytic activity enhancement of Ag/AgBr heterostructures could be attributed to the surface plasmon resonance and its synergistic effect on the photosensitive AgBr. Furthermore, a mechanism of the plasmon synergistically enhanced photocatalytic process was proposed.

References

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