Concepedia

Stoichiometric Aerobic Pt<sup>II</sup>−Me Bond Cleavage in Aqueous Solutions to Produce Methanol and a Pt<sup>II</sup>(OH) Complex

Andrei N. Vedernikov, S.A. Binfield, Peter Y. Zavalij, Julia R. Khusnutdinova

Journal of the American Chemical Society · 2005 · 106 citations · 9 references

DOI

Concepts

Abstract

Di(2-pyridyl)methanesulfonate ligand allows for facile aerobic oxidation of a PtIIMe complex into PtIVMe(OH)2 species and clean C-O reductive elimination of methanol from the latter in either acidic or basic aqueous solutions.

References

9

Platinum Catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative

Roy A. Periana, Douglas J. Taube, Scott Gamble et al. · Science · 1998 · 1.3K citations

, , +17

The Lost Colony and Jamestown Droughts

David W. Stahle, Malcolm K. Cleaveland, Dennis B. Blanton et al. · Science · 1998 · 268 citations

, , +12

Mild, Aqueous, Aerobic, Catalytic Oxidation of Methane to Methanol and Acetaldehyde Catalyzed by a Supported Bipyrimidinylplatinum−Polyoxometalate Hybrid Compound

I. Bar-Nahum, Alexander M. Khenkin, Ronny Neumann · Journal of the American Chemical Society · 2004 · 188 citations

, , +15

Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen

Vsevolod V. Rostovtsev, Lawrence M. Henling, Jay A. Labinger et al. · Inorganic Chemistry · 2002 · 144 citations

, , +12

Mechanism and stereochemistry for nucleophilic attack at carbon of platinum(IV) alkyls: model reactions for hydrocarbon oxidation with aqueous platinum chlorides

Gerrit A. Luinstra, Jay A. Labinger, John E. Bercaw · Journal of the American Chemical Society · 1993 · 127 citations

, , +7