Dalton Transactions · 2012 · 129 citations · 36 references
EngineeringMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologySensorsElectrochemical DetectionElectrochemical SensorsElectrode MaterialsNanosensorsSupercapacitor MaterialsSupercapacitorsCatalytic NanoparticlesCo OxidationCycle LifeElectrochemical NanosensorsElectrode FabricationNanorodsOxidationSupercapacitor Nanomaterials
Dendrite-like Co(3)O(4) nanostructure, made up of many nanorods with diameters of 15-20 nm and lengths of 2-3 μm, has been successfully prepared by calcining the corresponding nanostructured Co-8-hydroxyquinoline coordination precursor in air. The Co(3)O(4) nanostructure was evaluated as an electrochemical sensor for H(2)O(2) detection and the results reveal that it has good linear dependence and high sensitivity to H(2)O(2) concentration changes. As an electrode material of a supercapacitor, it was found that the nanostructured Co(3)O(4) electrode exhibits high specific capacitance and long cycle life. The Co(3)O(4) nanostructure also has good catalytic properties and is steadily active for CO oxidation, giving 100% CO conversion at low temperatures. The multifunctional Co(3)O(4) nanostructure would be a promising functional nanomaterial applied in multi industrialized fields.
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Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
Jesse L. C. Rowsell, E.C. Spencer, Juergen Eckert et al. · Science · 2005 · 895 citations · Full text