Self‐Supported Formation of Needlelike Co₃O₄ Nanotubes and Their Application as Lithium‐Ion Battery Electrodes

Abstract

A one-step, self-supported topotactic transformation approach for synthesizing electrochemically active Co3O4 needlelike nanotubes is reported. Used as the active material in the negative electrode of a rechargeable lithium ion battery, the Co3O4 nanotubes manifest ultrahigh Li storage capacity with improved cycle life and rate capability. These features are discussed in terms of the unique structure of the materials. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2089/2008/c2412_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.