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Electrical Conductivity Modulation Coupled to a High-Spin−Low-Spin Conversion in the Molecular System [Fe<sup>III</sup>(qsal)<sub>2</sub>][Ni(dmit)<sub>2</sub>]<sub>3</sub>·CH<sub>3</sub>CN·H<sub>2</sub>O

149

Citations

11

References

2006

Year

Abstract

The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal)2][Ni(dmit)2]3.CH3CN.H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

References

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