Diiron μ-vinylcarbyne complexes have unusually low barriers to vinyl rotation because conjugation is maintained throughout rotation

Quantum chemistry program exchange

Donald B. Boyd · Chemometrics and Intelligent Laboratory Systems · 1987 · 1.1K citations

Natural Sciences, Chemistry, Physics +9

Electronic structure and bonding in methyl- and perfluoromethyl(pentacarbonyl)manganese

Michael B. Hall, Richard F. Fenske · Inorganic Chemistry · 1972 · 531 citations

Natural Sciences, Chemistry, Inorganic Chemistry +11

Molecular orbital theory of the electronic structure of molecules. 39. Highly unusual structures of electron-deficient carbon compounds. Reversal of van't Hoff stereochemistry in BBC ring systems

Karsten Krogh‐Jespersen, Dieter Cremer, Dieter Poppinger et al. · Journal of the American Chemical Society · 1979 · 86 citations

Natural Sciences, Chemistry, Physics +15

Restricted Rotation in Aromatic Aldehydes

Frank A. L. Anet, Mohd Rozi Ahmad · Journal of the American Chemical Society · 1964 · 79 citations

Natural Sciences, Chemistry, Analytical Chemistry +6

Methyl-substituted allyl cations. A comparison of experimental stability, rotational barrier, and solvolysis data with ab initio calculations

Herbert Mayr, W. FOERNER, Paul von Ragué Schleyer · Journal of the American Chemical Society · 1979 · 67 citations

Natural Sciences, Chemistry, Chemical Kinetics +10