Concepedia

Structure Elucidation and Synthesis of Flavonol Acylglycosides. III.. The synthesis of tiliroside

Barbara Vermes, Vedanta Mohan Chari, Hildebert Wagner

Helvetica Chimica Acta · 1981 · 25 citations · 6 references

DOI

Concepts

Abstract

Abstract Naturally occurring kaempferol 3‐ O ‐β‐ D ‐(6″‐ O ‐coumaroyl)glucopyranoside (tiliroside) has been synthesized thereby confirming its structure. This is the first acylated flavonoid glycoside to be synthesized.

References

6

The chloroacetyl group in synthetic carbohydrate chemistry

Maurice J. Bertolini, C.P.J. Glaudemans · Carbohydrate Research · 1970 · 116 citations

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The conversion of benzyl 3-O-benzoyl-4,6-O-benzylidene-β-d-galactopyranoside into the 2-benzoate by acyl migration

G. J. F. CHITTENDEN, J. G. Buchanan · Carbohydrate Research · 1969 · 56 citations

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Flavonoids of the fruits and leaves of Tribulus terrestris: Constitution of tribuloside

Saachi Bhutani, S.S. Chibber, T. R. Seshadri · Phytochemistry · 1969 · 50 citations

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Acylated flavonol glucosides of Pinus contorta needles

Ryuichi Higuchi, Dervilla M. X. Donnelly · Phytochemistry · 1978 · 48 citations

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Confirmation of the structure of tiliroside, an acylated kaempferol glycoside, by 13C-nuclear magnetic resonance.

Masanori Kuroyanagi, Masamichi Fukuoka, Kunitoshi Yoshihira et al. · Chemical and Pharmaceutical Bulletin · 1978 · 36 citations · Full text

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