Concepedia

2<i>H</i>‐Chromenes Generated by an Iron(III) Complex‐Catalyzed Allylic Cyclization

L. Calmus, Andrei Corbu, Janine Cossy

Advanced Synthesis & Catalysis · 2015 · 26 citations · 39 references

DOI

Concepts

Abstract

Abstract A straightforward method based on an iron(III) complex‐catalyzed cyclization of 2‐(1‐hydroxyallyl)phenols is reported to access a large variety of 2 H ‐chromenes. This method was applied to the total synthesis of a natural product, tephrowatsin B. magnified image

References

39

Natural Product-like Combinatorial Libraries Based on Privileged Structures. 1. General Principles and Solid-Phase Synthesis of Benzopyrans

K. C. Nicolaou, Jeffrey A. Pfefferkorn, Anthony J. Roecker et al. · Journal of the American Chemical Society · 2000 · 674 citations

, , +13

Pt<sup>IV</sup>-Catalyzed Cyclization of Arene−Alkyne Substrates via Intramolecular Electrophilic Hydroarylation

Stefan J. Pastine, So Won Youn, Dalibor Sameš · Organic Letters · 2003 · 272 citations

, , +16

Chiral Organic Contact Ion Pairs in Metal-Free Catalytic Asymmetric Allylic Substitutions

Magnus Rueping, Uxue Uria, Ming‐Yuan Lin et al. · Journal of the American Chemical Society · 2011 · 246 citations

, , +11

Recent extensions of the Morita–Baylis–Hillman reaction

Guangning Ma, Jia‐Jun Jiang, Min Shi et al. · Chemical Communications · 2009 · 188 citations

, , +6

Synthesis of Chiral Chromans by the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA):  Scope, Mechanism, and Applications

Barry M. Trost, Hong C. Shen, Li Dong et al. · Journal of the American Chemical Society · 2004 · 179 citations

, , +11