Journal of the Physical Society of Japan · 1976 · 17 citations · 3 references
Natural SciencesChemistryNuclear ChemistryNuclear PhysicsSpectroscopyCoordination ChemistryHyperfine StructureMagnetic Resonance SpectroscopyNuclear SpinNuclear StructureHyperfine InteractionsHyperfine SpectroscopyNuclear Magnetic Resonance AnalysisNuclear Magnetic Resonance StudiesNuclear Quadrupole ResonanceNuclear Spin AssignmentsQuadrupole InteractionQuadrupole Splitting
The NMR of copper nuclei in CsCuCl 3 has been studied at 1.77 K. NMR lines of Cu 63 nuclei were observed at 169.2 MHz with two satellite lines equally split by the quadrupole interaction. The analyses of the hyperfine field and the quadrupole splitting give that the spin direction of the Cu 2+ ions is parallel to the local z -axis. Since the local z -axes have a helical nature along the c -axis, a screw spin arrangement at the ordered state is verified from the NMR results.
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<i>The Principles of Nuclear Magnetism</i>
A. Abragam, H. Y. Carr · Physics Today · 1961 · 570 citations