Berichte der Bunsengesellschaft für physikalische Chemie · 1988 · 109 citations · 12 references
Natural SciencesChemical EngineeringChemistryAnalytical ChemistryElectrochemistrySpectroscopyChemical OxidationInfrared SpectroscopyOxidation ReactionsRedox ChemistryRedox-active MaterialsSurface OxidationAdsorbate CharacterizationAlcohol OxidationFourier TransformMethane OxidationPlatinum ElectrodesReaction Intermediates SpectroscopySurface Adsorption SpectroscopySurface Chemistry Of Oxidation
Abstract The adsorbate formed during ethanol oxidation in acidic solutions is studied by Fourier transform infrared reflection‐absorption spectroscopy (FTIR) at constant potential, on‐line (DEMS) and thermal desorption mass spectroscopy (ECTDMS). – As in the case of methanol adsorbate CO ad was identified by FTIR and in addition COH ad by ECTDMS. On‐line MS experiments showed the formation of methane during the cathodic sweep of the voltammogram. Main products of ethanol oxidation from the bulk are carbon dioxide and acetaldehyde.
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Advances Infrared and Raman Spectroscopy
A.J.B · Journal of Molecular Structure · 1984 · 477 citations
Natural Sciences, Chemistry, Physics +14
The adsorption of CO, O2, and H2 on Pt
D. M. Collins, W. E. Spicer · Surface Science · 1977 · 301 citations