Organic Letters · 2006 · 87 citations · 6 references
Natural SciencesChemistryMolecular RecognitionSupramolecular ChemistryAnion RecognitionLigand BindingReceptor BindingReceptor-ligand InteractionsStructural Basis Of RecognitionAnion AffinityAnion Receptor DesignChemical Recognition
To explore the anion recognition ability of silanol hydroxy groups, a silanediol-based receptor 1 was prepared. Spectroscopic studies and X-ray crystallography revealed that the receptor exhibits the characteristic recognition of anions via two hydrogen bonds in chloroform.
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