Syntheses, Structures, and Solid State Properties of One-Dimensional Halogen-Bridged Ni<sup>111</sup>−X-Ni<sup>111</sup>Compounds (X˭Cl and Br)

K. Toriumi, Hiroshi Okamoto, T. Mitani, Shunji Bandow, Masahiro Yamashita, Yoshiki Wada, Y. Fujii, Robin J. H. Clark, D. J. Michael, A. J. Edward,

Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics · 1990 · 25 citations · 27 references

Concepts

Abstract

Abstract Halogen-bridged linear-chain compounds, {[Ni(R,R-chxn)2X]X2}∞ (X˭C1 and Br), were synthesized and their structures have been determined by low-temperature X-ray diffraction analyses. The novel one-dimensional Ni111 -X-Ni111 structure with no Peierls distortion, which is an extreme limit of the MII -X-MIV mixed-val

References

27