Frequency Conversion in a High<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>Q</mml:mi></mml:math>-Factor Sapphire Whispering Gallery Mode Resonator due to Paramagnetic Nonlinearity

Abstract

Nonlinear frequency conversion is a well known and widely exploited family of effects in optics, often arising from a Kerr nonlinearity in a crystal medium. Here, we report high stability frequency conversion in the microwave regime due to a χ(3) nonlinearity in sapphire introduced by a dilute concentration of paramagnetic spins. First, we produce a high stability comb from two microwave fields at 12.029 and 12.037 GHz corresponding to two high Q-factor whispering gallery (WG) modes within the electron spin resonance bandwidth of the Fe3+ ion. The resulting comb is generated by a cascaded four-wave mixing effect with a 7.7 MHz repetition rate. Then, by suppressing four-wave mixing by increasing the threshold power, third harmonic generation is achieved in a variety of WG modes coupled to various species of paramagnetic ion within the sapphire.