Concepedia

Synthesis and Characterization of [(C<sub>5</sub>Me<sub>5</sub>)Mn(CO)<sub>2</sub>(SR)]; RS Radicals as Ligands

Andreas Winter, Gottfried Hüttner, László Zsolnai, Peter M. H. Kroneck, Margarete Gottlieb

Angewandte Chemie International Edition in English · 1984 · 22 citations · 5 references

DOI

Concepts

Abstract

The deep-violet paramagnetic manganese complexes 2 can be obtained from 1 by reaction with thioles and oxygen. According to the EPR spectrum of 2a the unpaired electron resides in a MO with highly metallic character. The compounds 2 can be reversibly reduced cyclovoltammetrically.

References

5

CpM(CO)2(ligand) (Cp = cyclopentadienyl, M = metal) complexes

Birgitte E. R. Schilling, Roald Hoffmann, Dennis L. Lichtenberger · Journal of the American Chemical Society · 1979 · 351 citations

, , +9

An electron spin resonance study of the radical anions derived from metal carbene complexes of chromium, molybdenum, and tungsten

Paul J. Krusic, U. Klabunde, Charles P. Casey et al. · Journal of the American Chemical Society · 1976 · 86 citations

, , +11

Metal Ion Activation of Dioxygen

H. A. O. Hill · Biochemical Society Transactions · 1981 · 69 citations

, , +7

C<sub>5</sub>H<sub>5</sub>(CO)<sub>2</sub>Mn(<i>m</i>‐Toluidinyl), An Isolable Aminyl Complex

Dieter Sellmann, Jürgen Müller, Peter Hofmann · Angewandte Chemie International Edition in English · 1982 · 34 citations

, , +6

RS-verbrückte Carbonyl-Wolfram-Komplexe / RS-Bridged Carbonyl Tungsten Complexes

Andreas Winter, Olaf Scheidsteger, Gottfried Hüttner · Zeitschrift für Naturforschung B · 1983 · 12 citations · Full text

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