Concepedia

The Crystal Structure of Di-μ-Bromo-tris(triphenylphosphine)dicopper(II)

Hisao Negita, Morio Hiura, Yoshihiko Kushi, Masahiro Kuramoto, Tsutomu Okuda

Bulletin of the Chemical Society of Japan · 1981 · 16 citations · 5 references

DOI

Concepts

Abstract

Abstract The crystal structure of the Cu2Br2(PPh3)3·1.5C6H6 complex has been determined by three dimensional X-ray analysis. The crystals are monoclinic, and the space group is P21/c, with unit-cell parameters of a=14.122 (3), b=19.573 (4), c=25.985 (7) Å, β=128.99 (1)°, and Z=4. In the Cu2Br2(PPh3)3 molecule, one copper atom is three-coordinate, and the other, four-coordinate.

References

5

Complexes of copper (I) with triphenylphosphine

G. Costa, E. Reisenhofer, Laura Stefani · Journal of Inorganic and Nuclear Chemistry · 1965 · 86 citations

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Synthesis and properties of sulfur dioxide adducts of organophosphinecopper(I) iodides. Structures of the dinuclear compounds tetrakis(methyldiphenylphosphine)di-.mu.-iodo-dicopper(I)-sulfur dioxide and tris(triphenylphosphine)di-.mu.-iodo-dicopper(I)

P. G. Eller, Gregory J. Kubas, R. R. Ryan · Inorganic Chemistry · 1977 · 71 citations

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Structure of dichlorotris(triphenylphosphine)dicopper(I)-benzene, a chloride-bridged dimer containing both three- and four-coordinate copper

David F. Lewis, Stephen J. Lippard, P. S. Welcker · Journal of the American Chemical Society · 1970 · 49 citations

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Factors influencing the stereochemistry of four-coordinate copper(I)-phosphine complexes

Stephen J. Lippard, Gus J. Palenik · Inorganic Chemistry · 1971 · 41 citations

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Zeeman effect on the nqr of the complex of copper(I) halide with triphenylphosphine

Hisao Negita, Morio Hiura, Koji Yamada et al. · Journal of Molecular Structure · 1980 · 28 citations

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