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A highly reactive functional model for catechol 1,2-dioxygenase: reactivity studies of iron(iii) catecholate complexes of bis[(2-pyridyl)methyl][(1-methylimidazol-2-yl)methyl]amine
59
Citations
3
References
1997
Year
EngineeringMethanolOrganic ChemistryReactivity StudiesChemistryReactive Functional ModelRedox BiologyCatecholate ComplexesChemical EngineeringMethanol ReactsBioorganometallic ChemistryOrganometallic CatalysisRedox ChemistryInorganic ChemistryBiochemistryEfficient Catalytic ActivityCatalysisCatalytic SynthesisNatural SciencesVarious CatecholsSynthetic Chemistry
The system consisting of an iron(III) salt and bis[(2-pyridyl)- methyl][(1-methylimidazol-2-yl)methyl]amine (bpia) in methanol reacts with various catechols with insertion of dioxygen; in the case of 3,5-di-tert-butylcatechol the efficient catalytic activity of the system is shown.
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