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Paramagnetic 1H NMR spectroscopy of the reduced, unbound Photosystem I subunit PsaC: sequence-specific assignment of contact-shifted resonances and identification of mixed-and equal-valence Fe-Fe pairs in [4Fe-4S] centers FA − and FB −

MagnetismMagnetic PropertiesEngineeringNmr SpectroscopyContact-shifted ResonancesPhotosystemsParamagnetic 1HSpectroscopyElectron Paramagnetic ResonanceMagnetic ResonanceMolecular BiologyStructural BiologyProtein NmrNuclear Magnetic Resonance SpectroscopyMedicineBiophysics