Standoff LIBS measurements of energetic materials using a 266nm excitation laser

Robert D. Waterbury, Avishekh Pal, Dennis K. Killinger, Jeremy Rose, Edwin L. Dottery, G. P. Ontai

Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE · 2008 · 12 citations · 0 references

Concepts

Abstract

A Deep-UV LIBS system has been constructed for the standoff detection of Explosives, and potentially Chemical, Biological, Radiological, and Nuclear (CBRN) substances. A Q-Switched Nd:YAG Laser operating in at 266nm was used for excitation of the LIBS plasma and future Raman excitation. This plasma was enhanced by the means of a nearly simultaneous CO<sub>2</sub> laser which results in a method referred to as Townsend Effect Plasma Spectroscopy (TEPS). Spectra covering the range of 240-800nm at standoff distances are presented. The classical emission lines (i.e. C, N, O, H, etc) of the energetic samples were observed and a peak ratio technique was used to differentiate between benign and energetic samples of interest.