Synthetic study of polyoxypeptin: stereoselective synthesis of (2S,3R)-3-hydroxy-3-methylproline

The first practical method for asymmetric epoxidation

Tsutomu Katsuki, K. Barry Sharpless · Journal of the American Chemical Society · 1980 · 2.6K citations

Asymmetric Epoxidation, Altmetrics, Engineering +12

Phosphorus in organic synthesis—VII

Kunihiro Ninomiya, Takayuki Shioiri, Susumu Yamada · Tetrahedron · 1974 · 363 citations

Organic Chemistry, Synthetic Chemistry, Organic Synthesis—vii +1

Palladium catalyzed stereospecific cyclization of hydroxy epoxides. Stereocontrolled synthesis of cis- and trans-2-alkenyl-3-hydroxytetrahydropyrans

Toshio Suzuki, Ohki Sato, Masahiro Hirama · Tetrahedron Letters · 1990 · 79 citations

Enantioselective Synthesis, Engineering, Stereospecific Cyclization +7

Polyoxypeptins A and B Produced by <i>Streptomyces</i>:  Apoptosis-Inducing Cyclic Depsipeptides Containing the Novel Amino Acid (2<i>S</i>,3<i>R</i>)-3-Hydroxy-3-methylproline

Kazuo Umezawa, Kumi Nakazawa, Yoko Ikeda et al. · The Journal of Organic Chemistry · 1999 · 76 citations

Solvent Extraction, Bioorganic Chemistry, Apoptosis +18

Polyoxypeptin isolated from Streptomyces: A bioactive cyclic depsipeptide containing the novel amino acid 3-hydroxy-3-methylproline

Kazuo Umezawa, Kumi Nakazawa, Toshio Uemura et al. · Tetrahedron Letters · 1998 · 67 citations

Biotransformation, Biochemistry, Natural Sciences +6