Synthesis of β-heteroaryl propionates via trapping of carbocations with π-nucleophiles

Methodology for the construction of quaternary carbon centers

Stephen F. Martin · Tetrahedron · 1980 · 378 citations

Carbon Sequestration, Carbonization, Engineering +3

Asymmetric Brønsted Acid Catalysis: Enantioselective Nucleophilic Substitutions and 1,4‐Additions

Magnus Rueping, Boris J. Nachtsheim, Stefan A. Moreth et al. · Angewandte Chemie International Edition · 2007 · 347 citations

Engineering, Executive Decision, Biochemistry +14

Chiral Phosphoric Acid Catalyzed Enantioselective Friedel–Crafts Alkylation of Indoles with Nitroalkenes: Cooperative Effect of 3 Å Molecular Sieves

Junji Itoh, Kohei Fuchibe, Takahiko Akiyama · Angewandte Chemie International Edition · 2008 · 307 citations

Engineering, Cooperative Effect, Organic Chemistry +16

Sequential One-Pot InBr₃-Catalyzed 1,4- then 1,2-Nucleophilic Addition to Enones

Marco Bandini, Pier Giorgio Cozzi, Massimo Giacomini et al. · The Journal of Organic Chemistry · 2002 · 260 citations

Asymmetric Catalysis, Beta-substituted Ketones, Engineering +10

Organocatalytic Asymmetric Alkylation of Aldehydes by S_N1‐Type Reaction of Alcohols

Pier Giorgio Cozzi, Fides Benfatti, Luca Zoli · Angewandte Chemie International Edition · 2009 · 252 citations · Full text

Cross-coupling Reaction, Novel Organocatalysts, Engineering +12