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Synthese und Struktur eines aminstabilisierten Sulfens, RHC=SO<sub>2</sub> · N(CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>CH / Synthesis and Structure of an Amine Stabilized Sulfene, RHC=SO<sub>2</sub> · N(CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>CH

Uwe Hartwig, Hans Pritzkow, Wolfgang Sundermeyer, Joachim Waldi

Zeitschrift für Naturforschung B · 1988 · 16 citations · 0 references

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Abstract

The structure of the quinuclidine-stabilized mesyl sulfene H 3 C-SO 2 -CH=SO 2 ←N(CH 2 CH 2 ) 3 CH (3) was determined by X-ray analysis, which indicates a double-bond in the C=SO 2 group, while the quinuclidine is coordinated at a distance to the sulfur atom longer than a S-N single bond.