AIChE Journal · 2007 · 68 citations · 25 references
EngineeringChemical EngineeringMaterials ScienceMultiphase FlowPolymer ChemistryPolymer EngineeringDroplet DynamicsEmulsion FormationPolymerization ProcessesPolymerization Reaction EngineeringDroplet BreakupDroplet Breakup MechanismsDroplet Size ControlDroplet Size DistributionEmulsion ModelingHigh-pressure Emulsification
Abstract The mechanisms involved in the formation of high solids content composite polymer–monomer waterborne miniemulsions in a high‐pressure homogenizer were investigated combining experimental results and a mathematical model for the process. It was found that the final droplet size was the result of two consecutive processes: droplet break‐up and coagulation. The final droplet size was determined by the mechanism giving the largest droplet size © 2007 American Institute of Chemical Engineers AIChE J, 2008
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