The Journal of Organic Chemistry · 2010 · 99 citations · 91 references
Natural SciencesChemical EngineeringChemistryCatalysisOrganic ChemistryCatalyst PreparationCross-coupling ReactionsAryl Halide CouplingHeterocyclic Natural ProductsHiyama CouplingNanoparticlesPalladium CatalystsPalladium-catalyzed Cross-couplingSilane Coupling
An efficient Hiyama coupling reaction between benzylic halide and aryltrialkoxysilane using Pd nanoparticles has been developed. This procedure accommodates various functional groups to yield a diverse range of diarylmethanes which are ubiquitous units of natural products and pharmaceuticals.
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