A triphenylamine-based benzoxazole derivative as a high-contrast piezofluorochromic material induced by protonation

Pengchong Xue, Peng Chen, Junhui Jia, Qiuxia Xu, Jiabao Sun, Boqi Yao, Zhenqi Zhang, Ran Lu

Chemical Communications · 2014 · 208 citations · 34 references

Concepts

Abstract

A triphenylamine-based benzoxazole derivative (<bold>BVDP</bold>) as a typical D–π–A molecule could be used as a low contrast piezofluorochromic material with a spectral red-shift of 29 nm. However, when<bold>BVDP</bold>bound a proton to form<bold>BVDP+H</bold>, a high contrast piezofluorochromism (Δ<italic>λ</italic>= 75 nm) could be observed.

References

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