High regioselectivity in the alternative cleavage of terminal epoxides with different sources of nucleophilic fluoride

Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model

Michael J. S. Dewar, Eve G. Zoebisch, Eamonn F. Healy et al. · Journal of the American Chemical Society · 1985 · 13.1K citations

Natural Sciences, Chemistry, Physics +10

Fluorides and fluoro acids. Part 18. The system pyridine-hydrogen fluoride at low temperatures. Formation and crystal structures of solid complexes with very strong NHF and FHF hydrogen bonding

D. Boenigk, Dietrich Mootz · Journal of the American Chemical Society · 1988 · 137 citations

Natural Sciences, Chemistry, Materials Science +10

Regioselective opening of simple epoxides with diisopropylamine trihydrofluoride

Manfred Muehlbacher, C. Dale Poulter · The Journal of Organic Chemistry · 1988 · 68 citations

Natural Sciences, Chemistry, Medicinal Chemistry +7

Et3n.2Hf, a new convenient reagent for nucleophilic fluorine displacement reactions

Marie-Béatrice Giudicelli, D. PICQ, B. Veyron · Tetrahedron Letters · 1990 · 60 citations

Natural Sciences, Chemistry, Organic Chemistry +6

A stereocontrolled access to vicinal difluoroalkanes

Takeshi Hamatani, Seijiro Matsubara, Hiroyuki Matsuda et al. · Tetrahedron · 1988 · 51 citations

Pharmacy, Medicinal Chemistry, Drug Clearance +1