Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics · 1972 · 106 citations · 0 references
Natural SciencesChemistryPhysicsInorganic ChemistryPhysical ChemistrySpectroscopyChemical BondingElectronic Band StructureInorganic SpectroscopyMolecular Orbital TheoryPhotoelectron SpectroscopyElectronic Structure AnalysisSilicon ChemistryValence Band StructureValence Electronic Structure
Photoelectron spectra of (MH3)2Y and MH3SH (M = C,Si,Ge; Y = O,S,Se,Te) have been observed and the bands assigned to the expected valence-shell energy levels. The results are consistent with the existence of (p→d)π-bonding for all the compounds with M = Si,Ge.