The Journal of Chemical Physics · 1953 · 36 citations · 4 references
Natural SciencesChemistryMaterials ScienceTransport PhenomenaDiffusion In SolidsDiffusion ThermodynamicsHigh-pressure ThermodynamicsSolid-state DiffusionCarbon DisulfideDiffusion CoefficientsDiffusion In LiquidsDiffusion Under High PressurePressure-temperature RelationshipsSelf-diffusionTemperature Dependence Of Diffusion
A method has been developed for measuring diffusion coefficients in liquids to 10 000 atmospheres pressure. Measurements have been made over this pressure range at 0°, 20°, and 40°C for the system CS2–CSS35. The results are interpreted in terms of the enthalpy, entropy, and volume of activation as a function of temperature and pressure.
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