Satellite measurements of hydroxyl in the mesosphere

Abstract

The global distribution of hydroxyl (OH) in the middle atmosphere was recently measured by the Middle Atmosphere High Resolution Spectrograph Investigation (MAHRSI) on a satellite deployed and retrieved by the space shuttle. During 75 orbits, MAHRSI acquired 1800 daytime limb scans of the OH ultraviolet solar resonance fluorescence intensity. Each limb scan extends over the altitude region from 30 to 90 km and across 10° of latitude between 53°S and 63°N. OH number densities were retrieved using a Twomey regularization scheme constrained by the smoothness of the retrieved profile. Results provide a detailed description of the diurnal variation of mesospheric OH. Midmorning OH densities had a well defined peak of about 6 ×10 6 cm³ near 70 km, a broad minimum centered near 64 km, and rose to about 1 × 10 7 cm³ at 50 km. This profile is in substantial disagreement with photochemical model predictions [Summers et al., this issue]. The observations are compared with the two previous measurements.