Concepedia

Stereochemical proof of the existence of nucleophilic activation at a silicon atom in nucleophilic substitution reactions. Substitution of the SiCl-bond with retention of configuration

Robert J. P. Corriu, G. Dabosi, M. Martineau

Journal of Organometallic Chemistry · 1978 · 69 citations · 12 references

DOI

References

12

Stereochemistry of Asymmetric Silicon. I. Relative and Absolute Configurations of Optically Active α-Naphthylphenylmethylsilanes

Leo H. Sommer, C. L. Frye, G. A. Parker et al. · Journal of the American Chemical Society · 1964 · 198 citations

, , +15

Displacement Reactions of Phosphorus(<scp>V</scp>) Compounds and Their Pentacoordinate Intermediates

Paul Gillespie, Fausto Ramírez, Ivar Ugi et al. · Angewandte Chemie International Edition in English · 1973 · 172 citations

, , +11

The siliconium ion question

Robert J. P. Corriu, M. Henner · Journal of Organometallic Chemistry · 1974 · 167 citations

, , +3

Organosilicon Chemistry: The Mechanisms of Hydrolysis of Triphenylsilyl Fluoride and Triphenylmethyl Fluoride in 50% Water-50% Acetone Solution

C. Gardner Swain, Ramon M. Esteve, Richard H. Jones · Journal of the American Chemical Society · 1949 · 55 citations

, , +13

725. Nucleophilic substitution reactions of organosilicon compounds. Part II. Reaction mechanisms of some sterically hindered organosilicon chlorides

Annette D. Allen, G. MODENA · Journal of the Chemical Society (Resumed) · 1957 · 38 citations

, , +9