Concepedia

η<sup>1</sup>and η<sup>2</sup>complexes of λ<sup>3</sup>-1,2,4,6-thiatriazinyls with CpCr(CO)<sub>x</sub>

Chwee Ying Ang, Renè T. Boeré, Lai Yoong Goh, Lip Lin Koh, Seah Ling Kuan, Geok Kheng Tan, Xin Yu

Chemical Communications · 2006 · 18 citations · 21 references

DOI

Concepts

Abstract

The title heterocyclic radicals coordinate to either 17e CpCr(CO)3 or 15e CpCr(CO)2 moieties as one-electron or as three-electron donors, respectively; in the former the bonding is via the perpendicular p orbital of the sulfur atom, while in the latter bonding is via p(pi) orbitals on both sulfur and nitrogen.

References

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