Concepedia

An octanuclear pyromellitimidato(2−) palladium complex: coordinative assembly of a molecular box

Howard M. Colquhoun, Richard A. Fairman, P. Tootell, David J. Williams

Journal of the Chemical Society Dalton Transactions · 1999 · 15 citations · 9 references

DOI

Concepts

Abstract

Reaction of pyromellitimide with the binuclear palladium complex [Pd2(µ-Cl2)(1,2-C6H4NMe2)2] in the presence of base affords a box-like, pyromellitimidato(2–), octapalladium complex exhibiting helical chirality, for which 1H NMR and single crystal X-ray data are reported.

References

9

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Metal‐Induced Self‐Assembly of Cavitand‐Based Cage Molecules

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A Novel Highly Charged (+12) Anion Receptor That Encapsulates Simultaneously NO3− and PF6− Ions

R.-D. Schnebeck, E. Freisinger, Bernhard Lippert · Angewandte Chemie International Edition · 1999 · 169 citations

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