Concepedia

9,10‐Benzotricyclo[6.2.2.0<sup>2,7</sup>]dodeca‐3,5,9,11‐tetraene—A Diels‐Alder Adduct of Benzene and Naphthalene

Wolfram Grimme, Hans Günter Köser

Angewandte Chemie International Edition in English · 1980 · 19 citations · 5 references

DOI

Concepts

Abstract

Only indirectly accessible, the Diels-Alder adduct of the two simplest arenes (1) warrants attention; it has now been synthesized for the first time. Cycloreversion to benzene and naphthalene has been studied kinetically.

References

5

Frontier molecular orbital theory of cycloaddition reactions

K. N. Houk · Accounts of Chemical Research · 1975 · 795 citations

, , +8

Orbital energy control of cycloaddition reactivity

Reiner Sustmann · Pure and Applied Chemistry · 1974 · 402 citations · Full text

, , +9

<b>Reaction of Benzyne with Benzene and Naphthalene</b>

Roy G. Miller, Martin K. Stiles · Journal of the American Chemical Society · 1963 · 100 citations

, , +4

Heats of hydrogenation. X. Conjugative interaction in cyclic dienes and trienes

Richard B. Turner, Barbara J. Mallon, M. Tichý et al. · Journal of the American Chemical Society · 1973 · 100 citations

, , +11

(3—6‐η‐Tricyclo [6.2.2.0<sup>2,7</sup>] dodeca‐3,5,9,11‐tetraene)‐tricarbonyliron, a Stable Transition Metal Complex of “<i>o</i>,<i>p</i>′‐Dibenzene”

Wolfram Grimme, Ernst Schneider · Angewandte Chemie International Edition in English · 1977 · 28 citations

, , +6