Concepedia

(3—6‐η‐Tricyclo [6.2.2.0<sup>2,7</sup>] dodeca‐3,5,9,11‐tetraene)‐tricarbonyliron, a Stable Transition Metal Complex of “<i>o</i>,<i>p</i>′‐Dibenzene”

Wolfram Grimme, Ernst Schneider

Angewandte Chemie International Edition in English · 1977 · 28 citations · 11 references

DOI

Concepts

Abstract

The Diels-Alder dimer of benzene has now been synthesized in the form of the stable tricarbonyliron complex (1). On liberation by oxidizing cleavage, the dimer immediatedly decomposes to benzene.

References

11

Cyclobutadiene- and Benzocyclobutadiene-Iron Tricarbonyl Complexes<sup>1</sup>

G. F. Emerson, L. Watts, R. Pettit · Journal of the American Chemical Society · 1965 · 300 citations

, , +5

Cycloadditions of dichloroketene to olefins and dienes

Léon Ghosez, R. Montaigne, Albert Roussel et al. · Tetrahedron · 1971 · 142 citations

, , +5

Selective trapping of dienes by benzylideneacetoneiron tricarbonyl. Synthetic and mechanistic studies of the reactions of 1,3,5-cyclooctatriene and its derivatives with benzylideneacetoneiron tricarbonyl

Charles R. Graham, Gary Scholes, Maurice Brookhart · Journal of the American Chemical Society · 1977 · 51 citations

, , +7

Efficient syntheses of barrelene and Nenitzescu's hydrocarbon

W. G. DAUBEN, G. T. RIVERS, R. J. Twieg et al. · The Journal of Organic Chemistry · 1976 · 46 citations

, , +6

Directed synthesis of cis-anti-cis-tricyclo[6.4.0.02,7]dodecatetraene (o,o'-dibenzene). Thermal rearrangement of a blocked dibenzene to a caged (CH)12 precursor

Jerome A. Berson, Richard F. Davis · Journal of the American Chemical Society · 1972 · 37 citations

, , +9