Novel rearrangement reactions in the fluorination of methyl 3-C-methyl-3-nitro-α-l-hexopyranosides by the DAST reagent

Stereospecific 1,2-migrations in carbohydrates. Stereocontrolled synthesis of .alpha.- and .beta.-2-deoxyglycosides

K. C. Nicolaou, T. Ladduwahetty, J. L. Randall et al. · Journal of the American Chemical Society · 1986 · 219 citations

Engineering, Glycosylation, Biochemistry +12

Synthesis of 2'-C-.beta.-fluorodaunomycin. An example of configurational retention in fluorodehydroxylation with diethylaminosulfur trifluoride

Sergio Castillón, A. DESSINGES, R. Faghih et al. · The Journal of Organic Chemistry · 1985 · 53 citations

Diethylaminosulfur Trifluoride, Medicinal Chemistry, Bioorganic Chemistry +13

A facile formation of 2,5-anhydro sugars by ring contraction in methyl hexopyranoside 2-triflates under conditions of nucleophilic displacement

Hans H. Baer, Fernando Hernández-Matéo, Lisa Siemsen · Carbohydrate Research · 1989 · 46 citations

Facile Formation, Engineering, Biochemistry +7

The Reaction of Methyl 3-<u>O</u>-Benzyl-4, 6-<u>O</u>-benzylidene-α-D-mannopyranqside with Diethylaminosulfur Trifluoride (DAST)

Pavol Kováč, Herman J. C. Yeh, Grace L. Jung et al. · Journal of Carbohydrate Chemistry · 1986 · 26 citations

Diethylaminosulfur Trifluoride, Derivative (Chemistry), Natural Product Synthesis +11

Structural studies of 1,3-dioxa-2-silacycloalkanes

A. W. Hanson, A. W. McCulloch, A. G. McInnes · Canadian Journal of Chemistry · 1986 · 26 citations

Materials Science, Crystal Structure, Engineering +11