Concepedia

An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones

Hai‐Tao Zhu, Mingjin Fan, De‐Suo Yang, Xiao‐Ling Wang, Sen Ke, Chaoyang Zhang, Zheng‐Hui Guan

Organic Chemistry Frontiers · 2015 · 36 citations · 49 references

DOI

Concepts

Abstract

A facile and efficient iodine-promoted Meyer–Schuster rearrangement of propargyl alcohols for the synthesis of α-iodo-α,β-unsaturated ketones is presented.

References

49

Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

Alois Fürstner, Paul Davies · Angewandte Chemie International Edition · 2007 · 2.3K citations

, , +16

Molecular diversity through gold catalysis with alkynes

Eloísa Jiménez‐Núñez, Antonio M. Echavarren · Chemical Communications · 2006 · 805 citations

, , +14

AuCl<sub>3</sub>-Catalyzed Synthesis of Highly Substituted Furans from 2-(1-Alkynyl)-2-alken-1-ones

Tuanli Yao, Xiaoxia Zhang, Richard C. Larock · Journal of the American Chemical Society · 2004 · 487 citations

, , +16

Recent Advances on the Lewis Acid-Catalyzed Cascade Rearrangements of Propargylic Alcohols and Their Derivatives

Yuanxun Zhu, Lang Sun, Ping Lü et al. · ACS Catalysis · 2014 · 264 citations

, , +11

Oxidation of Silyl Enol Ethers by Using IBX and IBX⋅N-Oxide Complexes: A Mild and Selective Reaction for the Synthesis of Enones

K. C. Nicolaou, David Gray, Tamsyn Montagnon et al. · Angewandte Chemie International Edition · 2002 · 249 citations

, , +4