Journal of the Chemical Society Chemical Communications · 1972 · 11 citations · 0 references
Natural SciencesChemistryNuclear ChemistryOrganometallic ChemistrySpectroscopyCoordination ChemistryInorganic SpectroscopyMagnetism Of Inorganic CompoundsMetal-ligand BondingNuclear StructureTransition Metal ComplexesElectronic Spectra Of Transition Metal ComplexesFluorine ChemistryMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesNuclear Magnetic Resonance StudiesPlatinum CompoundsSpectroscopic Characterization Of Metal-ligand BondsSpectroscopy Of Transition Metal Complexes
19 F N.m.r. spectra of [MF(PR3)3][BF4], M = Pd or Pt, unequivocally confirm the assigned structures and comparison of coupling parameters with those in isostructural hydrido-complexes suggests a very small s character for the platinum–fluorine bond.