Concepedia

Selective Oxidation of Sulfides to Sulfoxides by Atmospheric Oxygen and Aldehyde Catalysed by NI<sup>II</sup>Complexes

Stéphane P. Vincent, Claude Lion, Mir Hedayatullah, Anthony Challier, Gérard Delmas, Gilbert Magnaud

Phosphorus, sulfur, and silicon and the related elements · 1994 · 12 citations · 9 references

DOI

Concepts

Abstract

Abstract A new and efficient method for oxidising sulfides selectively to sulfoxides has been developed with atmospheric oxygen, in the presence of isobutyraldehyde and catalysed by NiII complexes such as bis[1,3-bis-(p-methoxyphenyl)-1,3-propanedionato]nickel, [Ni(dmp)2], and bis[acetylacetonato]nickel, [Ni(acac)2]. Key Words: SulfidesoxidationsulfoxidesoxygenNi complexes.

References

9

Synthesis of sulfoxides by oxidation of thioethers

M. Madesclaire · Tetrahedron · 1986 · 304 citations

, , +2

Direct Epoxidation of Olefins Catalyzed by Nickel(II) Complexes with Molecular Oxygen and Aldehydes

Tohru Yamada, Toshihiro Takai, Oliver Rhode et al. · Bulletin of the Chemical Society of Japan · 1991 · 171 citations · Full text

, , +13

Oxidation of organic substrates by a molecular oxygen/aldehyde/heteropolyoxometalate system

Masatoshi Hamamoto, Kouichi Nakayama, Yutaka Nishiyama et al. · The Journal of Organic Chemistry · 1993 · 143 citations

, , +7

Selective molecular oxygen oxidation of thio ethers to sulfoxides catalyzed by cerium(IV)

Dennis P. Riley, Milton R. Smith, Paul E. Correa · Journal of the American Chemical Society · 1988 · 68 citations

, , +10

Selective autoxidation of electron-rich substrates under elevated oxygen pressures

Paul E. Correa, Gordon E. Hardy, Dennis P. Riley · The Journal of Organic Chemistry · 1988 · 55 citations

, , +8