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Metastable One-Dimensional AgCl<sub>1</sub><sub>-</sub><i><sub>x</sub></i>I<i><sub>x</sub></i> Solid-Solution Wurzite “Tunnel” Crystals Formed within Single-Walled Carbon Nanotubes
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2002
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Solid Solution CrystalsEngineeringChemistrySingle-walled Carbon NanotubesTunneling MicroscopyNanoelectronicsNanostructure SynthesisNanoscale ScienceMaterials SciencePhysicsCrystal MaterialNanotechnologyNanocrystalline MaterialOne-dimensional MaterialNanomaterialsNatural SciencesSurface ScienceApplied PhysicsCondensed Matter PhysicsIncorporated Halide CrystalsElectron Loss SpectroscopyFunctional Materials
High-resolution transmission electron microscopy and spatially resolved electron loss spectroscopy have revealed that a eutectic mixture of AgCl and AgI crystallizes within single walled carbon nanotubes (SWNTs) as metastable AgCl(1-)(x)I(x) 1D solid solution crystals. The incorporated halide crystals form wurzite "tunnel" structures with locally varying Cl:I ratios and reduced Ag coordination.
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