Publication | Closed Access
Isomerization of Perezone into Isoperezone and Preparation of Dihydroisoperezinone
21
Citations
8
References
1994
Year
BiosynthesisEngineeringBiochemistryNatural Sciences3,4,5,6-Tetrahydro-2-pyrimidinethiol 11Organic ChemistryPerezone 1Stereoselective SynthesisChemistry1,2-Carbonyl TranspositionHeterocycle ChemistryNatural Product SynthesisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract The reaction of perezone 1 with 3,4,5,6-tetrahydro-2-pyrimidinethiol 11 promotes a 1,2-carbonyl transposition in the quinoid ring of 1 giving rise to isoperezone 8, which treated with BF3·Et2O produces dihydroisoperezinone 9.
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