Journal of the Chemical Society D Chemical Communications · 1971 · 74 citations · 0 references
Inorganic ChemistryMagnetic PropertiesC ShiftsEngineeringPhysicsNatural SciencesCoordination ComplexDiamagnetic Transition-metal ComplexesLigands CoMolecular ComplexMain Group ChemistryChemistrySpectra-structure Correlation
13 C Shifts of diamagnetic transition-metal complexes for the ligands CO, CN–, CNR, COMe, Me, σ-Ph, C-(carbene), π-C2H4, π-arene, and π-allyl show very wide variations, and, specifically for the series (π-C5H5)Fe-(CO)3–nXn, very significantly with X.