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A Palladium Complex Promoted Asymmetric Synthesis of a Novel P-Chiral Diphosphine Containing an Ester Functional Group
18
Citations
7
References
1998
Year
Cross-coupling ReactionEngineeringChiral Organopalladium ComplexOrganic ChemistryOrganometallic CatalysisCarbon SkeletonChemistryPure P-chiral DiphosphineStereoselective SynthesisEster Functional GroupAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
A chiral organopalladium complex promoted asymmetric Diels−Alder reaction between 1-phenyl-3,4-dimethylphosphole and [(E)-2-(ethoxycarbonyl)vinyl]diphenylphosphine gives a novel optically pure P-chiral diphosphine which bears an ester functional group on the carbon skeleton.
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