Publication | Closed Access
Asymmetric Baylis–Hillman reactions: catalysis using a chiral pyrrolizidine base
128
Citations
8
References
1998
Year
Enantiomeric ExcessEngineeringBiochemistryMethyl Vinyl KetonesNatural SciencesAsymmetric Baylis–hillman ReactionsOrganic ChemistryCatalysisChemistryPharmacologyAsymmetric CatalysisBaylis–hillman ReactionSynthetic ChemistryEnantioselective Synthesis
A novel chiral pyrrolizidine base 5 derived from L-proline promotes the Baylis–Hillman reaction of ethyl and methyl vinyl ketones with electron deficient aromatic aldehydes with moderate levels of enantiomeric excess.
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